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Title: A Novel Monomeric Tin(II) Phosphate, [N(C2H5NH3)3]3+[Sn(PO4)(HPO4)]3−•4H2O, Connected through Hydrogen Bonding
Authors: Ayyappan, S
Cheetham, A K
Natarajan, S
Rao, C N R
Keywords: Aluminum Phosphate
Issue Date: Aug-1998
Publisher: Academic Press Inc
Citation: Journal Of Solid State Chemistry 139(1), 207-210 (1998)
Abstract: The tin(II) phosphate, [N(C2H5NH3)3]3+[Sn(PO4)(HPO4)]3−4H2O, contains monomeric Sn2(PO4)2(HPO4)2units which form a hydrogen-bonded network with the TREN amine (TREN=N(C2H5NH3)3+3); triclinic, space groupP1 (no. 2),a=9.579(1),b=10.507(1),c=10.976(1) Å;α=72.93(1)°,β=78.03(1)°,γ=69.82(1)°,V=984.2(1) Å3,Z=2. The Sn2P2O4core of this unit is a common structural feature of open-framework tin phosphates and may play a role as a building block for this class of materials.
Description: Restricted Access
Other Identifiers: 0022-4596
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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