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dc.contributor.authorGovindaraj, A-
dc.contributor.authorFlahaut, E-
dc.contributor.authorLaurent, Ch-
dc.contributor.authorPeigney, A-
dc.contributor.authorRousset, A-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-03-21T05:43:07Z-
dc.date.available2012-03-21T05:43:07Z-
dc.date.issued1999-06-
dc.identifier0884-2914en_US
dc.identifier.citationJournal of Materials Research 14(6), 2567-2576 (1999)en_US
dc.identifier.urihttp://hdl.handle.net/10572/689-
dc.description.abstractCarbon nanotubes produced by the treatment of Mg1-x,MxAl2O4 (M = Fe, Co, or Ni; r = 0.1, 0.2, 0.3, or 0.4) spinels with an H-2-CH4 mixture at 1070 degrees C have been investigated systematically. The grains of the oxide-metal composite particles are uniformly covered by a weblike network of carbon nanotube bundles, several tens of micrometers long, made up of single-wall nanotubes with a diameter close to 4 nm. Only the smallest metal particles (< 5 nm) are involved in the formation of the nanotubes. A macroscopic characterization method involving surface area measurements and chemical analysis has been developed in order to compare the different nanotube specimens. An increase in the transition metal content of the catalyst yields more carbon nanotubes (up to a metal content of 10.0 wt% or x = 0.3), but causes a decrease in carbon quality. The best compromise is to use 6.7 wt% of metal (r = 0.2) in the catalyst, Co gives superior results with respect to both the quantity and quality of the nanotubes. In the case of Fe, the quality is notably hampered by the formation of Fe3C particles.en_US
dc.description.urihttp://dx.doi.org/10.1557/JMR.1999.0344en_US
dc.language.isoenen_US
dc.publisherMaterials Research Societyen_US
dc.rights© 1999 Materials Research Societyen_US
dc.subjectMetal-Ceramic Compositesen_US
dc.subjectSingle-Walled Nanotubesen_US
dc.subjectNanocomposite Powdersen_US
dc.subjectElectrical-Resistanceen_US
dc.subjectReduction Behavioren_US
dc.subjectChemical Synthesisen_US
dc.subjectGrowthen_US
dc.subjectAluminaen_US
dc.subjectMorphologyen_US
dc.subjectDisproportionationen_US
dc.titleAn investigation of carbon nanotubes obtained from the decomposition of methane over reduced Mg1-xMxAl2O4 spinel catalystsen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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