Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/57
Full metadata record
DC FieldValueLanguage
dc.contributor.authorThirumurugan, A-
dc.contributor.authorSanguramath, R A-
dc.contributor.authorRao, C N R-
dc.date.accessioned2011-03-04T06:19:56Z-
dc.date.available2011-03-04T06:19:56Z-
dc.date.issued2008-02-04-
dc.identifier0020-1669en_US
dc.identifier.citationInorganic Chemistry 47(3), 823-831 (2008)en_US
dc.identifier.urihttp://hdl.handle.net/10572/57-
dc.descriptionRestricted access.en_US
dc.description.abstractBy the employment of hydrothermal methods, four lead 1,3-cyclohexanedicarboxylates with the compositions Pb(1,3-CHDC)(H2O), I, [(OPb4)2(OH)2(C2O4)(1,3-CHDC)4]‚H2O, II, Pb2(1,3-CHDC)2(H2O), III, and (OPb3)(1,3-CHDC)2, IV, have been prepared and characterized. Of these, I and II have layered structures while III and IV have three- dimensional structures. I−III are hybrid structures possessing extended inorganic connectivity in one or two-dimensions (In, n ) 1 or 2) involving infinite Pb−O−Pb linkages along with zero or one-dimensional organic connectivity (Om, m ) 0 or 1). I contains two types of layers with different connectivities (I1O1 and I2O0). III is a truly 3-D hybrid compound with I2O1 type connectivity. IV has three-dimensional organic connectivity (O3) but no inorganic connectivity (I0). The conformation of the CHDC anion is e,e in I−III and a,e in IV. In all these compounds, the lead atom has hemi- or holodirected coordination geometry.en_US
dc.description.urihttp://dx.doi.org/10.1021/ic701323qen_US
dc.language.isoenen_US
dc.publisherThe American Chemical Societyen_US
dc.rights© 2008 The American Chemical Societyen_US
dc.subjectMetal-Organic Frameworksen_US
dc.subjectCyclohexanedicarboxylate Liganden_US
dc.subjectCrystal-Structureen_US
dc.subjectNickel Succinateen_US
dc.subjectDicarboxylatesen_US
dc.subjectTerephthalateen_US
dc.subjectCden_US
dc.subjectTemperatureen_US
dc.subjectComplexesen_US
dc.subjectPolymersen_US
dc.titleHybrid Structures Formed by Lead 1,3-Cyclohexanedicarboxylatesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

Files in This Item:
File Description SizeFormat 
2008 Inorg.Chem. 47, 823.pdf
  Restricted Access
964.49 kBAdobe PDFView/Open Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.