Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/464
Title: Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites
Authors: Choudhury, Amitava
Kumar D, Udaya
Rao, C N R
Keywords: crystal growth
iron
magnetic properties
mesoporous materials
selenium
Iron Phosphate
Crystal-Structure
Hydrothermal Synthesis
Microporous Compounds
Magnetic-Properties
Networks
Form
Fef3
Issue Date: 2002
Publisher: WILEY-VCH Verlag GmbH
Citation: Angewandte Chemie-International Edition 41(1), 158-161 (2002)
Abstract: One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F3(SeO3)2] (I), which was synthesized hydrothermally from FeCl3⋅6 H2O, HF, and SeO2 in the presence of the organic amine piperazine. The same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.
Description: Restricted Access
URI: http://hdl.handle.net/10572/464
Other Identifiers: 1433-7851
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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