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Title: Organically Templated Mixed-Valent Iron Sulfates Possessing Kagome and Other Types of Layered Networks
Authors: Paul, Geo
Choudhury, Amitava
Sampathkumaran, E V
Rao, C N R
Keywords: hydrothermal synthesis
Kagome lattice
layered structures
magnetic properties
Ordered Magnetic Frustration
Issue Date: 2002
Publisher: WILEY-VCH Verlag GmbH
Citation: Angewandte Chemie-International Edition 41(22), 4297-4300 (2002)
Abstract: A perfect Kagomé lattice is displayed by the mixed-valent layered structure of [HN(CH2)6NH][FeIIIFeequation imageF6(SO4)2]⋅[H3O] (see picture), in which 100 % of the iron sites are occupied. The complex exhibits unusual magnetic properties; both magnetic frustration and ferrimagnetic behavior are observed.
Description: Restricted Access
Other Identifiers: 1433-7851
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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