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Title: Aliphatic dicarboxylates with three-dimensional metal-organic frameworks possessing hydrophobic channels
Authors: Vaidhyanathan, Ramanathan
Natarajan, Srinivasan
Rao, C N R
Keywords: Crystal-Structure
Coordination Polymer
Cobalt(Ii) Carboxylate
Hydrothermal Synthesis
Microporous Solids
Building Units
Issue Date: 2003
Publisher: Royal Society Chemistry
Citation: Dalton Transactions (8), 1459-1464 (2003)
Abstract: Two three-dimensional open-framework metal dicarboxylates possessing channels with a hydrophobic environment have been synthesized. One is a malonate of the formula, [Cd(O2C-CH2-CO2)(H2O)].H2O, I, and the other a glutarate of the formula [Mn(O2C-(CH2)(3)-CO2)], II. The three-dimensional structure of I is attained through infinite Cd-O-Cd corner-linkages. On the other hand, II, contains Mn-O-Mn layers cross-linked by MnO6 octahedra and glutarate moieties.
Other Identifiers: 1477-9226
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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