Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/443
Title: Solvothermal Synthesis of a Layered Open-Framework Chlorocadmium Oxalate, Cd2(C2O4)0.5Cl3NaCl·4H2O
Authors: Vaidhyanathan, R
Natarajan, Srinivasan
Rao, C N R
Keywords: materials science
cadmium
solvothermal synthesis
metathesis
Hydrothermal Synthesis
X-Ray
Crystal-Structure
Cadmium Oxalates
Chemistry
Units
Phosphates
Clusters
Channels
Behavior
Issue Date: May-2003
Publisher: WILEY-VCH Verlag GmbH
Citation: European Journal Of Inorganic Chemistry (9), 1675-1680 (2003)
Abstract: The metathesis reaction between CdCl2.2H(2)O and sodium oxalate in n-hexanol under solvothermal conditions yields a hybrid compound of formula Cd-2(C2O4)(0.5)Cl3NaCl.4H(2)O, It consists of one-dimensional chains formed by Cd and Cl atoms, containing mu(2)(Cl) and mu(3)(Cl) bridges, and cross-linked by oxalate units to give a layered structure. The Na+ ions and water molecules occupy the interlamellar spaces. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
Description: Restricted Access
URI: http://hdl.handle.net/10572/443
Other Identifiers: 1434-1948
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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