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dc.contributor.authorPadmanabhan, M-
dc.contributor.authorJosephx, James C-
dc.contributor.authorThirumurugan, A-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-02-07T06:50:37Z-
dc.date.available2012-02-07T06:50:37Z-
dc.date.issued2008-
dc.identifier1477-9226en_US
dc.identifier.citationDalton Transactions (21), 2809-2811 (2008)en_US
dc.identifier.urihttp://hdl.handle.net/10572/316-
dc.description.abstractReaction of a molecular Co(II) maleate, [Co(Hmal)(2)(H2O)(4)], with pyridine yields a Co(II) fumarate, [Co(fum)(H2O)(4)], with a chain structure and a chiral pyridylsuccinic acid zwitter ion, -OOC-CH(N+C5H5)-CH2-COOH, in almost quantitative yields, while the reaction of 4,4'-bipyridine (bipy) with the Co(II) maleate, on the other hand, almost quantitatively generates a polylmeric Co(II) maleate, [Co(mal)(bipy)](n) center dot(n/2) H2O along with the adduct of fumaric acid with bipyridine.en_US
dc.description.urihttp://dx.doi.org/10.1039/b718623aen_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rights© 2008 The Royal Society of Chemistryen_US
dc.subjectCrystal-Structureen_US
dc.subjectCoordination Polymersen_US
dc.subjectMagnetic-Propertiesen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectMetal Carboxylatesen_US
dc.subjectOpen Frameworken_US
dc.subjectMaleic-Aciden_US
dc.subject3-D Networken_US
dc.subjectComplexesen_US
dc.subjectCu(Ii)en_US
dc.titleMaleate–fumarate conversion and other novel aspects of the reaction of a Co(II) maleate with pyridine and bipyridineen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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