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Title: Maleate–fumarate conversion and other novel aspects of the reaction of a Co(II) maleate with pyridine and bipyridine
Authors: Padmanabhan, M
Josephx, James C
Thirumurugan, A
Rao, C N R
Keywords: Crystal-Structure
Coordination Polymers
Hydrothermal Synthesis
Metal Carboxylates
Open Framework
3-D Network
Issue Date: 2008
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions (21), 2809-2811 (2008)
Abstract: Reaction of a molecular Co(II) maleate, [Co(Hmal)(2)(H2O)(4)], with pyridine yields a Co(II) fumarate, [Co(fum)(H2O)(4)], with a chain structure and a chiral pyridylsuccinic acid zwitter ion, -OOC-CH(N+C5H5)-CH2-COOH, in almost quantitative yields, while the reaction of 4,4'-bipyridine (bipy) with the Co(II) maleate, on the other hand, almost quantitatively generates a polylmeric Co(II) maleate, [Co(mal)(bipy)](n) center dot(n/2) H2O along with the adduct of fumaric acid with bipyridine.
Other Identifiers: 1477-9226
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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