Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/2650
Title: Controlling the activity of organocatalysts: modulating conformation and acidity
Authors: Rajaram, Sridhar
Chittoory, Arjun Kumar
Keywords: Organocatalysts
Issue Date: 4-Sep-2017
Publisher: Jawaharlal Nehru Centre for Advanced Scientific Research
Citation: Chittoory, Arjun Kumar. 2017, Controlling the activity of organocatalysts: modulating conformation and acidity, Ph.D thesis, Jawaharlal Nehru Centre for Advanced Scientific Research, Bengaluru
Abstract: The catalyst-substrate interaction in organocatalysis is weaker than the corresponding interactions in organometallic catalysis. In the case of organocatalysis, non-covalent interactions (NCI) play an important role in enhancing these interactions. Conventionally, restricting the access of reactant to one face of a prochiral substrate is often accomplished by steric factors in an enantioselective process. In general the shape complementarity of the chiral binding pocket to the transition states of the reaction is a prerequisite for a stereoselective process. I
URI: http://lib.jncasr.ac.in:8080/jspui/handle/10572/2650
Appears in Collections:Student Theses (NCU)

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