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dc.contributor.authorHaldar, Ritesh
dc.contributor.authorMatsuda, Ryotaro
dc.contributor.authorKitagawa, Susumu
dc.contributor.authorGeorge, Subi Jacob
dc.contributor.authorMaji, Tapas Kumar
dc.date.accessioned2017-02-21T09:00:04Z-
dc.date.available2017-02-21T09:00:04Z-
dc.date.issued2014
dc.identifier.citationHaldar, R; Matsuda, R; Kitagawa, S; George, SJ; Maji, TK, Amine-Responsive Adaptable Nanospaces: Fluorescent Porous Coordination Polymer for Molecular Recognition. Angewandte Chemie-International Edition 2014, 53 (44) 11772-11777, http://dx.doi.org/10.1002/anie.201405619en_US
dc.identifier.citationAngewandte Chemie-International Editionen_US
dc.identifier.citation53en_US
dc.identifier.citation44en_US
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10572/2515-
dc.descriptionRestricted Accessen_US
dc.description.abstractFlexible and dynamic porous coordination polymers (PCPs) with well-defined nanospaces composed of chromophoric organic linkers provide a scaffold for encapsulation of versatile guest molecules through noncovalent interactions. PCPs thus provide a potential platform for molecular recognition. Herein, we report a flexible 3D supramolecular framework {[Zn(ndc)(o-phen)]center dot DMF}(n) (o-phen= 1,10-phenanthroline, ndc=2,6-napthalenedicarboxylate) with confined nanospaces that can accommodate different electron-donating aromatic amine guests with selective turn-on emission signaling. This system serves as a molecular recognition platform through an emission-readout process. Such unprecedented tunable emission with different amines is attributed to its emissive charge-transfer (CT) complexation with o-phen linkers. In certain cases this CT emission is further amplified by energy transfer from the chromophoric linker unit ndc, as evidenced by single-crystal X-ray structural characterization.en_US
dc.description.uri1521-3773en_US
dc.description.urihttp://dx.doi.org/10.1002/anie.201405619en_US
dc.language.isoEnglishen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.rights@Wiley-V C H Verlag Gmbh, 2014en_US
dc.subjectChemistryen_US
dc.subjectCharge Transferen_US
dc.subjectEnergy Transferen_US
dc.subjectMolecular Recognitionen_US
dc.subjectSupramolecular Encapsulationen_US
dc.subjectX-Ray Diffractionen_US
dc.subjectMetal-Organic Frameworksen_US
dc.subjectSelective Co2 Captureen_US
dc.subjectCharge-Transferen_US
dc.subjectEnergy-Transferen_US
dc.subjectMicroporous Metalen_US
dc.subjectAdsorptionen_US
dc.subjectSeparationen_US
dc.subjectTransformationen_US
dc.subjectLuminescenceen_US
dc.subjectTemperatureen_US
dc.titleAmine-Responsive Adaptable Nanospaces: Fluorescent Porous Coordination Polymer for Molecular Recognitionen_US
dc.typeArticleen_US
Appears in Collections:Research Articles (Tapas Kumar Maji)
Research Papers (Subi Jacob George)

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