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dc.contributor.authorSubbarao, Udumula
dc.contributor.authorGhosh, Aloke Kumar
dc.contributor.authorSarkar, Sumanta
dc.contributor.authorPeter, Sebastian C.
dc.date.accessioned2017-02-21T08:59:31Z-
dc.date.available2017-02-21T08:59:31Z-
dc.date.issued2014
dc.identifier.citationSubbarao, U; Ghosh, AK; Sarkar, S; Peter, SC, Crystal growth, structure and magnetic properties of Sm3Ni5Al19: A compound in the Sm2n+mNi4n+mAl15n+4m homologous series. Journal of Chemical Sciences 2014, 126 (5) 1605-1613, http://dx.doi.org/10.1007/s12039-014-0682-0en_US
dc.identifier.citationJournal of Chemical Sciencesen_US
dc.identifier.citation126en_US
dc.identifier.citation5en_US
dc.identifier.issn0974-3626
dc.identifier.urihttp://hdl.handle.net/10572/2504-
dc.descriptionRestricted Accessen_US
dc.description.abstractSm3Ni5Al19 was obtained as large rod shaped single crystals from reactive aluminium flux. Single crystal X-ray diffraction suggests that Sm3Ni5Al19 crystallizes in the Gd3Ni5Al19 structure type, orthorhombic space group Cmcm and lattice constants a = 4.0974(1) , b = 16.0172(6) and c = 27.0774(10) . Sm3Ni5Al19 is a member of the Sm2n+mNi4n+mAl15n+4m series with n = 1 and m = 1. The crystal structure of Sm3Ni5Al19 consists of SmNiAl4 and Sm2Al4Al15 slabs intergrown along the b-axis. Magnetic susceptibility data on Sm3Ni5Al19 confirms the paramagnetic nature with a complicated magnetic ordering below 18 K. The inverse susceptibility data follows modified Curie-Weiss law above 150 K with effective magnetic moment 1.3 mu (B)/Sm atoms suggests trivalent Sm atoms.en_US
dc.description.uri0973-7103en_US
dc.description.urihttp://dx.doi.org/10.1007/s12039-014-0682-0en_US
dc.language.isoEnglishen_US
dc.publisherIndian Academy of Sciencesen_US
dc.rights@Indian Academy of Sciences, 2014en_US
dc.subjectChemistryen_US
dc.subjectIntermetallicsen_US
dc.subjectCrystal Growthen_US
dc.subjectCrystal Structureen_US
dc.subjectMagnetismen_US
dc.subjectRare-Earthen_US
dc.subjectTernary Compoundsen_US
dc.subjectMixed-Valenten_US
dc.subjectIntermetallic Compoundsen_US
dc.subjectOrdered Superstructureen_US
dc.subjectReen_US
dc.subjectYben_US
dc.subjectBehavioren_US
dc.subjectFamilyen_US
dc.subjectSmen_US
dc.titleCrystal growth, structure and magnetic properties of Sm3Ni5Al19: A compound in the Sm2n+mNi4n+mAl15n+4m homologous seriesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Sebastian C. Peter)

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