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dc.contributor.authorShetty, Amitha
dc.contributor.authorSaha, Avijit
dc.contributor.authorMakkar, Mahima
dc.contributor.authorViswanatha, Ranjani
dc.date.accessioned2017-01-24T06:37:28Z-
dc.date.available2017-01-24T06:37:28Z-
dc.date.issued2016
dc.identifier.citationShetty, A.; Saha, A.; Makkar, M.; Viswanatha, R., Ligand assisted digestion and formation of monodisperse FeCoS2 nanocrystals. Physical Chemistry Chemical Physics 2016, 18 (37), 25887-25892 http://dx.doi.org/10.1039/c6cp04912een_US
dc.identifier.citationPhysical Chemistry Chemical Physicsen_US
dc.identifier.citation18en_US
dc.identifier.citation37en_US
dc.identifier.issn1463-9076
dc.identifier.urihttp://hdl.handle.net/10572/2222-
dc.descriptionRestricted Accessen_US
dc.description.abstractDigestive ripening of bimetallic magnetic nanocrystals from uniform microsheets to spherical nanocrystals was observed in FeCoS2 nanocrystals leading to the formation of monodisperse nanocrystals. Earlier examples of digestive ripening are associated with the transformation of polydisperse particles to monodisperse particles deriving energetic stabilization from the monodispersity. However, it is interesting to note that in the current case, not only did we observe a transformation from uniform sheets to spherical particles but we also observed it in the absence of thiol, the most commonly used digestive ripening agent. We have then studied the effect of ligands such as oleic acid and oleylamine responsible for this ripening process. Long chain acids were found to be majorly responsible for digestive ripening while the amines assist in the formation of microsheets. A plausible mechanism has then been proposed.en_US
dc.description.uri1463-9084en_US
dc.description.urihttp://dx.doi.org/10.1039/c6cp04912een_US
dc.language.isoEnglishen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rights@Royal Society of Chemistry, 2016en_US
dc.subjectChemistryen_US
dc.subjectPhysicsen_US
dc.subjectMagnetic Nanoparticlesen_US
dc.subjectSuperlattice Formationen_US
dc.subjectGold Nanoparticlesen_US
dc.subjectShape Controlen_US
dc.subjectSizeen_US
dc.subjectGrowthen_US
dc.subjectScaleen_US
dc.subjectFunctionalizationen_US
dc.subjectTemperatureen_US
dc.subjectMorphologyen_US
dc.titleLigand assisted digestion and formation of monodisperse FeCoS2 nanocrystalsen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Ranjani Viswanatha)

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