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dc.contributor.authorAvinash, M. B.
dc.contributor.authorSwathi, K.
dc.contributor.authorNarayan, K. S.
dc.contributor.authorGovindaraju, T.
dc.date.accessioned2017-01-24T06:35:05Z-
dc.date.available2017-01-24T06:35:05Z-
dc.date.issued2016
dc.identifier.citationAvinash, M. B.; Swathi, K.; Narayan, K. S.; Govindaraju, T., Molecular Architectonics of Naphthalenediimides for Efficient Structure-Property Correlation. Acs Applied Materials & Interfaces 2016, 8 (13), 8678-8685 http://dx.doi.org/10.1021/acsami.6b00011en_US
dc.identifier.citationACS Applied Materials & Interfacesen_US
dc.identifier.citation8en_US
dc.identifier.citation13en_US
dc.identifier.issn1944-8244
dc.identifier.urihttp://hdl.handle.net/10572/2203-
dc.descriptionRestricted Accessen_US
dc.description.abstractWe present a bioinspired design strategy to effectively tailor the assembly of naphthalenediimides (NDIs) into a wide variety of architectures by functionalizing with amino acid derivatives. This bioinspired process of custom designing and engineering molecular assemblies is termed "bioinspired architectonics". By employing minute structural mutations in the form of alpha-substituents of amino acids, we successfully engineered molecular assembly of NDIs into zero dimensional (OD, spheres), one-dimensional (ID, fibers), and two-dimensional (2D, sheets) architectures. The 2D sheets of phenylalanine methylester appended NDI I showed remarkable bulk electron mobility of up to 1 cm(2) V(-1)s(-1). With the aid of photophysical, diffraction, and microscopy techniques we rationalize the effect of molecular structure with their ordering and electronic properties in an effort to find structure property correlations via a bioinspired modular approach.en_US
dc.description.urihttp://dx.doi.org/10.1021/acsami.6b00011en_US
dc.language.isoEnglishen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights@American Chemical Society, 2016en_US
dc.subjectMaterials Scienceen_US
dc.subjectmolecular architectonicsen_US
dc.subjectself-assemblyen_US
dc.subjectstructure-property correlationen_US
dc.subjectelectron mobilityen_US
dc.subjectorganic semiconductorsen_US
dc.subjectField-Effect Transistorsen_US
dc.subjectCharge-Transporten_US
dc.subjectMetallic Conductivityen_US
dc.subjectOrganic Semiconductoren_US
dc.subjectDiimideen_US
dc.subjectNanoarchitectonicsen_US
dc.subjectOrganizationen_US
dc.subjectElectronen_US
dc.subjectSystemsen_US
dc.subjectNanosheetsen_US
dc.titleMolecular Architectonics of Naphthalenediimides for Efficient Structure-Property Correlationen_US
dc.typeArticleen_US
Appears in Collections:Research Articles (Narayan K. S.)
Research Papers (Govindaraju, T.)

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