Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/2146
Title: 2D coordination polymer composed of 1D {Ni-II(mu-O)(mu-H2O)Ni-II}(n) ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration
Authors: Adalikwu, Stephen Adie
Chakraborty, Anindita
Hazra, Arpan
Ghosh, Dibyajyoti
Pati, Swapan Kumar
Maji, Tapas Kumar
Keywords: Chemistry
Crystallography
Coordination polymer
Magnetism
Dehydration-rehydration
Guest responsive behavior
Density functional theory
Crystal-Structure
Spin-Crossover
Issue Date: 2016
Publisher: Pergamon-Elsevier Science Ltd
Citation: Adalikwu, S. A.; Chakraborty, A.; Hazra, A.; Ghosh, D.; Pati, S. K.; Maji, T. K., 2D coordination polymer composed of 1D {Ni-II(mu-O)(mu-H2O)Ni-II}(n) ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration. Polyhedron 2016, 115, 276-281 http://dx.doi.org/10.1016/j.poly.2016.05.011
Polyhedron
115
Abstract: Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA) (H2O)](n) (1) is reported which exhibits tunable magnetic behavior based on dehydration-rehydration. 1 shows ferromagnetic (FM) interaction between Ni-II ions. Combined detailed experimental and theoretical studies reveal that FM interaction arises due to "orthogonal" magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction. (C) 2016 Elsevier Ltd. All rights reserved.
Description: Restricted Access
URI: http://hdl.handle.net/10572/2146
ISSN: 0277-5387
Appears in Collections:Research Articles (Swapan Kumar Pati)
Research Articles (Tapas Kumar Maji)

Files in This Item:
File Description SizeFormat 
5.pdf
  Restricted Access
1.44 MBAdobe PDFView/Open Request a copy


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.