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dc.contributor.authorGoura, Joydeb
dc.contributor.authorWalsh, James P. S.
dc.contributor.authorTuna, Floriana
dc.contributor.authorHalder, Ritesh
dc.contributor.authorMaji, Tapas Kumar
dc.contributor.authorChandrasekhar, Vadapalli
dc.date.accessioned2016-12-22T11:26:56Z-
dc.date.available2016-12-22T11:26:56Z-
dc.date.issued2015
dc.identifier.citationCrystal Growth & Designen_US
dc.identifier.citation15en_US
dc.identifier.citation6en_US
dc.identifier.citationGoura, J.; Walsh, J. P. S.; Tuna, F.; Halder, R.; Maji, T. K.; Chandrasekhar, V., P-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymers. Crystal Growth & Design 2015, 15 (6), 2555-2560.en_US
dc.identifier.issn1528-7483
dc.identifier.urihttp://hdl.handle.net/10572/1955-
dc.descriptionRestricted accessen_US
dc.description.abstractThe reaction of lanthanide(III) salts with an organodiphosphonic acid under hydrothermal conditions resulted in a P-C bond cleavage affording [{Eu-4(PO4)(PO4)(0.5)x(4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (1), [{Dy-4(PO4)center dot(PO4)(0.5x4)(PO4)(0.25x4)(H2O)(2)}center dot 6H(2)O](n) (2), and [{Gd(PO4)(0.5)(PO4)(0.5)(H2O)(3)}center dot 2H(2)O](n) (3). 1 and 2 are porous 3D coordination polymers whose repeating units possess a dimeric motif. While one lanthanide ion in the dimer is eight-coordinate in a distorted square-antiprismatic geometry, the other is nine-coordinate and present in a distorted monocapped square-antiprismatic geometry. In contrast to 1 and 2, 3 possesses a 2D architecture; the asymmetric unit contains a monomeric Gd-III center which is nine-coordinate in a distorted monocapped square-antiprismatic geometry.en_US
dc.description.uri1528-7505en_US
dc.description.urihttp://dx.doi.org/10.1021/cg5017005en_US
dc.language.isoEnglishen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights?American Chemical Society, 2015en_US
dc.subjectChemistryen_US
dc.subjectCrystallographyen_US
dc.subjectMaterials Scienceen_US
dc.subjectSingle-Molecule-Magneten_US
dc.subjectMetal-Organic-Frameworken_US
dc.subjectPyrazole Ligandsen_US
dc.subjectAdsorption Propertiesen_US
dc.subjectCrystal-Structureen_US
dc.subjectSmm Behavioren_US
dc.subjectIon Magneten_US
dc.subjectLuminescenten_US
dc.subjectPhosphonateen_US
dc.subjectComplexesen_US
dc.titleP-C Bond Cleavage-Assisted Lanthanide Phosphate Coordination Polymersen_US
dc.typeArticleen_US
Appears in Collections:Research Articles (Tapas Kumar Maji)

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