Please use this identifier to cite or link to this item: http://lib.jncasr.ac.in:8080/jspui/handle/10572/1883
Title: Controlled synthesis of tunable nanoporous carbons for gas storage and supercapacitor application
Authors: Jayaramulu, Kolleboyina
Datta, Kasibhatta Kumara Ramanatha
Shiva, Konda
Bhattacharyya, Aninda J.
Eswaramoorthy, M.
Maji, Tapas Kumar
Keywords: Applied Chemistry
Physical Chemistry
Nanoscience & Nanotechnology
Materials Science
Nanoporous carbon
Metal-organic framework
Hydrogen storage
Carbon dioxide storage
Supercapacitor
Metal-Organic Frameworks
Porous Coordination Polymers
Mesoporous Carbon
Energy-Storage
Hydrogen Storage
Recent Progress
Adsorption
Functionalization
Nanocomposites
Electrodes
Issue Date: 2015
Publisher: Elsevier Science Bv
Citation: Microporous and Mesoporous Materials
206
Jayaramulu, K.; Datta, K. K. R.; Shiva, K.; Bhattacharyya, A. J.; Eswaramoorthy, M.; Maji, T. K., Controlled synthesis of tunable nanoporous carbons for gas storage and supercapacitor application. Microporous and Mesoporous Materials 2015, 206, 127-135.
Abstract: A simple methodology has been developed for the synthesis of functional nanoporous carbon (NPC) materials using a metal-organic framework (IRMOF-3) that can act as a template for external carbon precursor (viz, sucrose) and also a self-sacrificing carbon source. The resultant graphitic NPC samples (abbreviated as NPC-0, NPC-150, NPC-300, NPC-500 and NPC-1000 based on sucrose loading) obtained through loading different amounts of sucrose exhibit tunable textural parameters. Among these, NPC-300 shows very high surface area (BET approximate to 3119 m(2)/g, Langmuir approximate to 4031 m(2)/g) with a large pore volume of 1.93 cm(3)/g. High degree of porosity coupled with polar surface functional groups, make NPC-300 remarkable candidate for the uptake of H-2 (2.54 wt% at 1 bar, and 5.1 wt% at 50 bar, 77 K) and CO2 (64 wt% at 1 bar, 195 K and 16.9 wt% at 30 bar, 298 K). As a working electrode in a supercapacitor cell, NPC-300 shows excellent reversible charge storage thus, demonstrating multifunctional usage of the carbon materials. (C) 2015 Elsevier Inc. All rights reserved.
Description: Restricted access
URI: http://hdl.handle.net/10572/1883
ISSN: 1387-1811
Appears in Collections:Research Articles (Eswaramoorthy M.)

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