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Title: Synthesis and structure of [C3N2H5][Cu(H2PO4)(2)Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate
Authors: Neeraj, S
Loiseau, T
Rao, C N R
Cheetham, A K
Keywords: Open-Framework
Metal Phosphates
Hydrothermal Synthesis
Open Architectures
Cobalt Phosphate
Zinc Phosphates
Issue Date: Oct-2004
Publisher: Elsevier Science BV
Citation: Solid State Sciences 6(10), 1169-1173 (2004)
Abstract: A new one-dimensional copper (II) phosphate, [C3N2H5][Cu(H2PO4)(2)Cl](H2O)-H-., I, with pseudo-10-membered channels along the b-axis formed by the hydrogen bonded chains, containing imidazolium ions has been synthesized and characterized by single-crystal X-ray diffraction. The compound being the first example of an organically templated copper (II) phosphate, crystallizes in the monoclinic space group P2(1)/n (No. 14) with a = 8.9998(14) Angstrom, b = 7.0189(11) Angstrom, c = 18.986(3) Angstrom; beta = 102.964(3)degrees; V = 1168.8(3) Angstrom(3); Z = 4. The copper chlorophosphate chains in I are topologically similar to those observed in fornacite and vauquelinite. (C) 2004 Elsevier SAS. All rights reserved
Description: Restricted Access
Other Identifiers: 1293-2558
Appears in Collections:Research Papers (M.R.S. Rao)

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