Please use this identifier to cite or link to this item:
Title: Chiral and Achiral Malate Frameworks with Different Dimensionalities
Authors: Ghosh, Anupama
Rao, C N R
Keywords: malic acid
hybrid compounds
strontium malate
lead malate
Metal-Organic Frameworks
Coordination Polymers
Crystal- Structure
Structural Diversity
Aspartate Trihydrate
Issue Date: 2008
Publisher: Wiley-V C H Verlag Gmbh
Citation: Zeitschrift für anorganische und allgemeine Chemie 634(6-7), 1115-1122 (2008)
Abstract: A hybrid chain compound of the formula [Sr(L- C4H4O5)center dot 3H(2)O]center dot H2O (1) and a hybrid double layered compound of the formula [Pb(L- C4H4O5)] (2) both with chiral structures, have been prepared strarting with L- malic acid, and characterized by X-ray crystallography and other techniques. An achiral three-dimensional hybrid compound of the composition [Pb(D,L- C4H4O5)center dot 2H(2)O] (3) has been obtained starting with D, L- malic acid. A chiral coordination polymer of Cu-II with the formula [Cu-3(L-C4H3O5)(2)center dot 4H(2)O]center dot 2H(2)O (4) has also been characterized. The structures as well as the novel coordination modes exhibited by 1-4 are discussed.
Description: Restricted Access
Other Identifiers: 0044-2313
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

Files in This Item:
File Description SizeFormat 
  Restricted Access
898.14 kBAdobe PDFView/Open Request a copy

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.