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dc.contributor.authorDan, Meenakshi-
dc.contributor.authorSivashankar, K-
dc.contributor.authorCheetham, A K-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-11-23T08:59:33Z-
dc.date.available2012-11-23T08:59:33Z-
dc.date.issued2003-08-
dc.identifier0022-4596en_US
dc.identifier.citationJournal of Solid State Chemistry 174(1), 60-68 (2003)en_US
dc.identifier.urihttp://hdl.handle.net/10572/1053-
dc.descriptionRestricted Accessen_US
dc.description.abstractTwo layered amine-templated cobalt squarates, [C6N2H14](2)[Co-2(C4O4)(3)(H2O)(4)], I, and [C3N2H5](2)[CO2(C4O4)(3)(H2O)(4)], II, have been prepared under hydrothermal conditions. Both I and II contain chains formed by dimers comprising two cobalt atoms bound to the squarate units, the chains being connected through hydrogen bond interactions. An amine-templated cobalt squarate of the formula [C4N2H12][CO(C4O4)(2)(H2O)(4)][H2O](2), III, as well as its Ni, Zn and Cd analogues have been prepared by room temperature reactions. III has a layered architecture wherein the cobalt-squarate monomers are linked by the amine molecules. Co and Zn analogues of [Ni(C4O4)(H2O)(2)(C3N2H4)] with ligating imidazole units have also been prepared and characterized. (C) 2003 Elsevier Science (USA). All rights reserved.en_US
dc.description.urihttp://dx.doi.org/10.1016/S0022-4596(03)00174-9en_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.rights© 2003 Elsevier Scienceen_US
dc.subjectOrganic Frameworken_US
dc.subjectOxalatesen_US
dc.subjectSpectraen_US
dc.subjectCrystalen_US
dc.subjectNickelen_US
dc.subjectNien_US
dc.titleAmine-templated metal squaratesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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