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Title: Open-Framework Rubidium Halides Incorporated in Cadmium Oxalate Host Lattices
Authors: Vaidhyanathan, R
Natarajan, Srinivasan
Rao, C N R
Keywords: Directing Organic Amines
Cobalt(Ii) Carboxylate
Issue Date: Aug-2002
Publisher: Academic Press Inc Elsevier Science
Citation: Journal of Solid State Chemistry 167(2), 274-281 (2002)
Abstract: The metathetic reaction between CdBr2 and rubidium oxalate under hydrothermal conditions yields [RbBr] [Cd6(C2O4)(6)]. 2H(2)O, I, containing Cd6O24 clusters with the Br- ions in the center. The RbBr moiety forms a three-dimensional Fm3m structure, but with a unit cell double that of the normal stable phase. The hydrothermal reaction between rubidium oxalate and CdCl2 in the presence of NO3- ions gives [Rb2Cd(NO3)(Cl) (C2O4)(H2O)], II, containing cadmium chloro-oxalate layers. The Rb+ ions present between the layers interact with the Cl atoms to form a one-dimensional RbCl chain decorated by NOT groups. (C) 2002 Elsevier Science (USA).
Description: Restricted Access
Other Identifiers: 0022-4596
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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